Exfoliation of a non-van der Waals material from iron ore hematite

Exfoliation of a non-van der Waals material from iron ore hematite

Journal Article

Abstract

With the advent of graphene, the most studied of all two-dimensional materials, many inorganic analogues have been synthesized and are being exploited for novel applications. Several approaches have been used to obtain large-grain, high-quality materials. Naturally occurring ores, for example, are the best precursors for obtaining highly ordered and large-grain atomic layers by exfoliation. Here, we demonstrate a new two-dimensional material ‘hematene’ obtained from natural iron ore hematite (α -Fe2O3), which is isolated by means of liquid exfoliation. The two-dimensional morphology of hematene is confirmed by transmission electron microscopy. Magnetic measurements together with density functional theory calculations confirm the ferromagnetic order in hematene while its parent form exhibits antiferromagnetic order. When loaded on titania nanotube arrays, hematene exhibits enhanced visible light photocatalytic activity. Our study indicates that photogenerated electrons can be transferred from hematene to titania despite a band alignment unfavorable for charge transfer.

Details

PUBLISHED IN
Nature nanotechnology 2018
PUBLICATION DATE
07 מאי 2018
AUTHORS
Aravind Puthirath Balan, Sruthi Radhakrishnan, Cristiano F. Woellner, Shyam K. Sinha, Liangzi Deng, Carlos de los Reyes, Banki Manmadha Rao, Maggie Paulose, Ram Neupane, Amey Apte, Vidya Kochat, Robert Vajtai, Avetik R. Harutyunyan, Ching-Wu Chu, Gelu Costin, Douglas S. Galvao, Angel A. Martí, Peter A. van Aken, Oomman K. Varghese, Chandra Sekhar Tiwary, Anantharaman Malie Madom Ramaswamy Iyer, and Pulickel M. Ajayan